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1.
Late Paleozoic sedimentary strata outcrop extensively in central Inner Mongolia, and are a key to understanding the tectonic evolution of the southeastern Central Orogenic Belt. A combined analysis of petrography, whole-rock major and trace element, and Nd isotope is carried out on representative sandstones from the Late Paleozoic sedimentary strata (420–270 Ma). The sandstones are mainly wackes and litharenites in lithology, with low SiO2/Al2O3 of 2.85–9.47 (averagely 5.22) and poor textural and compositional maturities, implying short sediment transportation between the depositional basins and provenances. The trace element compositions are generally comparable to that of the average upper continent crust (UCC), with negatively-sloping chondrite-normalized rare earth element distribution patterns ((La/Yb)N = 3.43–11; averagely 6.94) and flat UCC-normalized trace element distribution patterns. The Nd isotopic compositions show great variation (ԐNd(t) = −5.01 to 5.35) with depositional time of the sandstones, and coincide well with the arc magmatic phases in central Inner Mongolia. The geochemical signatures of the sandstones indicate that the dominant provenances are intermediate to felsic arc magmatic rocks that have ages approximating the deposition, although old, recycled sediments may have made a minor contribution. An active continental arc setting during the Late Paleozoic in central Inner Mongolia, controlled by the northward subduction of the Paleo-Asian oceanic slab, was the most likely depositional tectonic setting of the sandstones. This active continental arc setting continued to at least 270 Ma, implying that the final closure of the Paleo-Asian Ocean along the Solonker suture zone most likely occurred sometime during the Late Permian to Early Triassic. The northward subduction of the Paleo-Asian Ocean is likely of West Pacific-style, in which the present-day Baolidao arc has a close genetic link with the South Mongolian microcontinent and, likely, the former originally formed as the arc margin of the latter.  相似文献   
2.
常规EA-IRMS硫同位素测试中, 硫化银(Ag2S)的需样量为0.2~1.0 mg, 硫酸钡(BaSO4)的需样量为0.35~1.5 mg, 较大的需样量已难以满足珍贵样品及微区样品的分析要求, 因此如何减少测试样品量已成为EA-IRMS测试分析工作中急需解决的问题。通过对EA-IRMS测试系统的研究发现, 在采用常规方法测试样品时, 由于初始He载气流速(100 mL/min)、进入分流接口时的流速(10 mL/min)与进入离子源时流速 (0.3 mL/min)的差异导致样品燃烧产生的目标气体中99.7%的气体被浪费, 样品的总体利用率仅有0.3%。因此如何减少样品在测试过程中的损耗, 提高样品的利用率, 从而减少需样量的关键在于缩小载气流速的差距。本实验在常规EA-IRMS测试技术基础上进行了关键改进,在元素分析仪和分流接口之间设计增加一个由六通阀和自动加热冷阱构成的装置, 自动加热冷阱可在Load模式时收集SO2气体, 六通阀在Load-Inject模式之间切换时可改变He载气流速, 通过与分流接口匹配的反吹He载气(10 mL/min)将冷阱中富集的SO2气体送入分流接口, 从而保证进入分流接口前样品燃烧产生的SO2气体全部收集。这一改进, 理论上可以将样品的利用率提高10倍, 该系统需硫量降至3~13 μg, 并且可以提高反应管的寿命, 降低清灰的频率, 提高工作效率。同时有效避免了拖尾的产生, 提高分析结果的精密度。本次微量样品实验获得的硫同位素数据与常规方法一致, 分析精度优于0.15‰(1SD), 测量值与真值的差异在0.4‰以内, 达到国际同类实验室先进水平。此外, 该方法可为微量有机碳、氮同位素EA-IRMS测试分析工作的开展提供参考经验。  相似文献   
3.
天山是全球第二大金矿富集区,世界级和大型-超大型金矿床东西成带横贯中国新疆中部—哈萨克斯坦东南部—吉尔吉斯斯坦—乌兹别克斯坦,构成巨型跨境金成矿带。天山巨型跨境金成矿带和重要金矿床形成的地质环境、成矿的控制要素、找矿勘查的标志都是学术界和工业界高度关注的重大地质和找矿问题。通过广泛、深入地文献调研和境内外天山较全面野外地质矿产调查与研究,本文认为中-哈-吉-乌天山大规模金成矿主体形成于晚石炭世—早二叠世古亚洲洋闭合后的陆块拼贴变形过程,部分形成于中—晚二叠世陆内走滑变形过程。中天山南、北缘古缝合带及其附近的大型脆性/韧-脆性变形带是巨量金成矿的关键控制因素,多期叠加复合成矿是天山变形带容矿金矿床的显著特征。地壳初始富集、构造变形活化、岩浆热液叠加是天山变形带容矿金矿床的主控因素。“碳质细碎屑岩+脆韧性变形带+海西末期岩体”是中-哈-吉-乌天山变形带容矿大型-超大型金矿的找矿标志组合。  相似文献   
4.
《China Geology》2020,3(4):633-642
Oil and gas resources are short in Pakistan and no commercially viable oil and gas sources have been yet discovered in its offshore areas up to now. In this study, the onshore-offshore stratigraphic correlation and seismic data interpretation were conducted to determine the oil and gas resource potential in the Offshore Indus Basin, Pakistan. Based on the comprehensive analysis of the results and previous data, it is considered that the Cretaceous may widely exist and three sets of source rocks may be developed in the Offshore Indus Basin. The presence of Miocene mudstones has been proven by drilling to be high-quality source rocks, while the Cretaceous and Paleocene–Eocene mudstones are potential source rocks. Tectonic-lithologic traps are developed in the northwestern part of the basin affected by the strike-slip faults along Murray Ridge. Furthermore, the Cretaceous and Paleocene–Eocene source rocks are thick and are slightly affected by volcanic activities. Therefore, it can be inferred that the northwestern part of Offshore Indus Basin enjoys good prospects of oil and gas resources.  相似文献   
5.
蓄集矿床是宗务隆构造带内发现的重要银铅矿床。蓄集银铅矿床赋存于石炭-二叠系宗务隆群果可山组灰岩夹千枚岩地层中,矿体呈脉状、透镜状、似层状,明显受近东西走向的断裂构造控制,矿体围岩蚀变主要为硅化和绢云母化,矿石矿物主要为方铅矿和银黝铜矿,脉石矿物主要为石英,矿石具有斑杂状和网脉状构造。对该矿床开展了S-Pb同位素组成分析。硫同位素分析结果表明矿石中硫化物矿物δ~(34)S值变化于5.0‰~8.4‰之间,显示硫主要为岩浆来源,有少量地层的贡献;铅同位素分析结果表明,矿石~(206)Pb/~(204) Pb=17.896~17.922,~(207)Pb/~(204) Pb=15.589~15.617,~(208) Pb/~(204) Pb=38.072~38.166,与围岩铅同位素组成(~(206) Pb/~(204) Pb=17.94~18.976,~(207)Pb/~(204) Pb=15.600~15.696,~(208) Pb/~(204) Pb=38.106~40.943)较为相似,而与蓄集峡口闪长岩铅同位素组成(~(206) Pb/~(204) Pb=18.144~18.589,~(207)Pb/~(204) Pb=15.623~15.636,~(208)Pb/~(204) Pb=38.790~39.033)相差较大,反映成矿物质主要来自围岩地层宗务隆群果可山组。综合分析认为,蓄集银铅矿床与宗务隆构造带晚二叠世岩浆活动关系密切,应属岩浆热液为主的热液充填-交代成因类型。  相似文献   
6.
甲玛矿床位于冈底斯成矿带东段,是西藏地区最大的铜多金属矿床之一。磁黄铁矿是甲玛矿床最常见的金属矿物之一,其标型特征不仅反映其自身形成环境,对其形成机制和矿床成因也具有指示意义。文章选取产于不同岩性中的磁黄铁矿矿石样品,利用矿相学、X射线衍射和电子探针分析等手段对磁黄铁矿的形态、成分和结构进行了分析研究。研究表明,甲玛矿床的磁黄铁矿主要分布在距离岩体中心较远的矿区远端矽卡岩和角岩中。磁黄铁矿的晶胞参数和粉晶X射线衍射曲线显示矽卡岩中的磁黄铁矿主要为高温六方磁黄铁矿,角岩中的磁黄铁矿为高温六方磁黄铁矿和低温单斜磁黄铁矿的交生体,但主要以低温单斜磁黄铁矿为主。通过对矽卡岩和角岩中的磁黄铁矿进行电子探针测试,结果显示:矽卡岩中的磁黄铁矿中w(Fe)为60.09%~60.71%,平均为60.38%,w(S)为38.18%~38.69%,平均38.35%,化学分子式为Fe_8S_9~Fe_(10)S_(11);角岩中的磁黄铁矿中w(Fe)为59.05%~59.57%,平均为59.10%,w(S)为39.28%~39.95%,平均39.59%,化学分子式为Fe_5S_6~Fe_7S_8。根据以上矿物学特征,笔者进一步探讨了该矿床磁黄铁矿的沉淀机制:炽热的岩浆热液上涌,与碳酸盐岩地层和碎屑岩地层接触发生相互作用,并有大气水的加入,使得成矿流体在角岩中先快速降温,形成高温六方磁黄铁矿和低温单斜磁黄铁矿的交生体。同时,大量的含矿热液形成,并充填于有利的成矿空间(主要为层间破碎带)沉淀成矿,形成矽卡岩矿体,然后流体在矽卡岩矿段中经历缓慢降温,形成高温六方磁黄铁矿。结合矿床地质特征和相关元素地球化学特征,认为甲玛矿床类型为斑岩-矽卡岩型。  相似文献   
7.
We review some issues relevant to volatile element chemistry during accretion of the Earth with an emphasis on historical development of ideas during the past century and on issues we think are important. These ideas and issues include the following: (1) whether or not the Earth accreted hot and the geochemical evidence for high temperatures during its formation, (2) some chemical consequences of the Earth’s formation before dissipation of solar nebular gas, (3) the building blocks of the Earth, (4) the composition of the Earth and its lithophile volatility trend, (5) chemistry of silicate vapor and steam atmospheres during Earth’s formation, (6) vapor - melt partitioning and possible loss of volatile elements, (7) insights from hot rocky extrasolar planets. We include tabulated chemical kinetic data for high-temperature elementary reactions in silicate vapor and steam atmospheres. We finish with a summary of the known and unknown issues along with suggestions for future work.  相似文献   
8.
Late Neoproterozoic-Early Cambrian calc-alkaline granitoids are ubiquitous in the continental basement of Iran and indicate formation within a Cadomian arc system at the northern margin of Gondwana. A basement complex comprising mainly mica schist, paragneisses, and metagranite along with metabasite and rare pegmatite is exposed in the Zayanderud region north of Shahrekord located in the hinterland of the Zagros mountain range. This complex is unique in the Neotethyan realm because it includes eclogites with Jurassic metamorphic ages implying involvement of continental crust at the onset of subduction. Ion microprobe UPb zircon dating along with trace element and oxygen isotope analyses for metagranites define two zircon age clusters of ca. 552 and 565 Ma confirming connection with the other Ediacaran age basement arc plutons in the belt. Zircon geochronology for pegmatite, by contrast, yielded a concordant age population averaging 176.5 ± 3.3 (2σ) Ma. Zircon crystals from the pegmatite also have unusually low rare earth element (REE) abundances with sharp increases towards the heavy REE. Along with an absence of a negative Eu anomaly, this indicates a high-grade metamorphic origin of zircon crystallizing from a pegmatite which was formed by melting of mica schist and possibly amphibole eclogite during decompression where incipient garnet breakdown released Zr and HREE to form zircon, and LREE were retained in stable apatite and titanite. Corresponding 40Ar/39Ar phengite dates from the pegmatite and the mica schist country-rock are overlapping with or only slightly postdate the UPb zircon ages, indicating rapid cooling after reaching maximum metamorphic pressure in the Early Jurassic. The Zayanderud basement complex is thus potentially a rare example of deep burial of continental crust and rapid exhumation due to buoyant escape during the incipient stages of subduction, well before the ultimate closing of the Neotethys ocean basin between Arabia and Eurasia in the mid-Tertiary.  相似文献   
9.
As the largest siliciclastic sink in the South China block, the Triassic Nanpanjiang basin is generally thought of as a foreland basin related to Indosinian collision between the South China and Indochina blocks. Our basin analysis, spanning an eight years period, provides details of Lopingian to Middle Triassic stratigraphic fill and tectonic subsidence of the basin. Field observation and sedimentological analyses reveal that the basin was not filled by a monotonous turbidite system and suggest instead the development of five primary depositional units constituted by deep-water turbidite systems, mass-transport deposits, condensed drapes, shallow-water isolated carbonate platforms, and volcano-volcaniclastic rocks. The stratigraphic completeness of the basin, the coexistence of widespread but localized carbonate platforms within axially filled deep-water basin, tectonically generated cyclothems of transverse mass-transport deposits along intrabasinal faults and basin fill of extrusive rocks of bimodal composition together apparently call in question the claim that crustal shortening prevailed during the Late Permian to pre-Norian Triassic. Patterns of basin fill, differential tectonic subsidence and very high subsidence rate of the region adjacent to master fault are more closely match the pattern expected for extensional to transtensional basin in a back-arc setting. The crustal extension in the southwestern South China was not consistent with hypothesized Indosinian collision between South China and Indochina blocks, but more likely developed in response to northwestward subduction of the paleo-Pacific plate. Our results, combined with regional considerations, lead to a new model for the Triassic tectonic evolution of South China during Triassic assembly of the southeastern and eastern Asia.  相似文献   
10.
The appearance of voluminous K-rich granitoids within nearly all ancient cratons represents one major characteristic of late Archean Earth, which hold the key to understand the transitional geodynamic regimes globally during this period. The genetic regimes and links among different K-rich granitoids and their implications for crustal growth and evolution remain controversial. A series of late Neoarchean K-rich granitoids, including quartz dioritic, granodioritic, and monzogranitic gneisses, occur in the Jiaobei terrane of North China Craton. Zircon U-Pb isotopic data reveal that they emplaced during ~2544–2494 Ma, coeval with regional ~2530–2470 Ma high-grade metamorphism.The quartz dioritic-granodioritic gneisses are magnesian rocks, and they show low Si and Ti, but high K and Mg, similar to Archean low-Ti sanukitoids. The Sr/Y and (La/Yb)N are high (mostly 59.99–119.32 and 8.56–61.42), with moderate to high Nb (up to 11.79 ppm). Geochemical modeling, combined with depleted zircon εHf(t2) (+0.5 − +7.2) and the presence of minor xenocrystic zircons, indicate that these low silica samples were derived from a metasomatized depleted mantle source with inputs of slab-derived fluids and melts, and minor contamination by ancient crustal materials. The monzogranitic rocks are ferroan rocks showing high Si, K, and Fe, but low Mg. They are divided into two subgroups: the first displays low TREE of 44.00–127.00 ppm and positive Eu anomalies (EuN/Eu*N = 1.06–1.60), whereas the second shows high TREE of 85.76–819.02 ppm but negative Eu anomalies (EuN/Eu*N = 0.51–0.62). Geochemical modeling and depleted zircon εHf(t2) of +2.6 − +8.4 suggest their formation by partial melting of juvenile crustal sources involving tonalitic and some metasedimentary rocks at diverse crustal levels.Combined with regional geological data, these late Neoarchean K-rich granitoids were generated by coupled melting of metasomatized depleted mantle and dominantly juvenile crustal materials during crustal stabilization. Furthermore, the Jiaobei terrane experienced ~2.6–2.5 Ga crustal growth under a subduction-accretion setting.  相似文献   
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